Neutron diffraction study of aluminous hydroxide δ-AlOOD

被引：0
作者：
C. B. Vanpeteghem
A. Sano
K. Komatsu
E. Ohtani
A. Suzuki
机构：
[1] Georgia Institute of Technology,School of Chemistry and Biochemistry
[2] Tohoku University,Institute of Mineralogy, Petrology and Economic Geology, Graduate School of Science
[3] The University of Edinburgh,Centre for Science at Extreme Conditions
[4] The University of Tokyo,Geochemical Laboratory, Graduate School of Science
[5] University of Tokyo,Institute for Solid State Physics
来源：
Physics and Chemistry of Minerals | 2007年 / 34卷
关键词：
Neutron diffraction; Hydrogen bond; Crystal structure;
D O I：
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学科分类号：
摘要：
We have determined the position of deuterium atoms in δ-AlOOD by neutron powder diffraction at ambient pressure. As previously reported by theoretical and experimental studies, the deuterium atoms are located in the tunnel formed by the chains of AlO6 octahedra. The data are best fit with the P21nm structure, producing bond lengths of D–O1 of 1.552(2) Å, O2–D of 1.020(2) Å and O1–O2 of 2.571(2). This study confirms that the hydrogen bond is asymmetric at ambient conditions in agreement with recent single-crystal synchrotron study for δ-AlOOH.
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页码：657 / 661
页数：4
相关论文
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