The Role of the Support in the Oxidative Destruction of Chlorobenzene on Pt/Zeolite Catalysts: An FT-IR Investigation

被引：0
|
作者：
Salvatore Scirè
Simona Minicò
机构：
[1] Università di Catania,Dipartimento di Scienze Chimiche
来源：
Catalysis Letters | 2003年 / 91卷
关键词：
catalytic combustion; chlorobenzene; platinum; H-ZSM5; H-ferrierite; FT-IR;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The deep oxidation of chlorobenzene was investigated over Pt/H-ferrierite and Pt/H-ZSM5 catalysts. Catalytic results showed that Pt/zeolite samples exhibit higher activity and lower by-products formation than Pt/γ-Al2O3, tested for comparison. Pt/H-ferrierite resulted to be the most favorable system as it leads to the lowest formation of noxious polychlorinated benzenes. The present FT-IR investigation pointed out that the support significantly affects the combustion of chlorobenzene over Pt/zeolite catalysts, support acidity directing the activity of the system and pore structure of the zeolite determining the level and the distribution of polychlorinated compounds.
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页码：199 / 205
页数：6
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