The Role of the Support in the Oxidative Destruction of Chlorobenzene on Pt/Zeolite Catalysts: An FT-IR Investigation

被引:0
|
作者
Salvatore Scirè
Simona Minicò
机构
[1] Università di Catania,Dipartimento di Scienze Chimiche
来源
Catalysis Letters | 2003年 / 91卷
关键词
catalytic combustion; chlorobenzene; platinum; H-ZSM5; H-ferrierite; FT-IR;
D O I
暂无
中图分类号
学科分类号
摘要
The deep oxidation of chlorobenzene was investigated over Pt/H-ferrierite and Pt/H-ZSM5 catalysts. Catalytic results showed that Pt/zeolite samples exhibit higher activity and lower by-products formation than Pt/γ-Al2O3, tested for comparison. Pt/H-ferrierite resulted to be the most favorable system as it leads to the lowest formation of noxious polychlorinated benzenes. The present FT-IR investigation pointed out that the support significantly affects the combustion of chlorobenzene over Pt/zeolite catalysts, support acidity directing the activity of the system and pore structure of the zeolite determining the level and the distribution of polychlorinated compounds.
引用
收藏
页码:199 / 205
页数:6
相关论文
共 50 条
  • [31] Raman, FT-IR and XRD investigation of natural opals
    Sodo, A.
    Municchia, A. Casanova
    Barucca, S.
    Bellatreccia, F.
    Della Ventura, G.
    Butini, F.
    Ricci, M. A.
    JOURNAL OF RAMAN SPECTROSCOPY, 2016, 47 (12) : 1444 - 1451
  • [32] Investigation of degree of gelatinization of cooked rice by FT-IR
    Ayabe, Sonoko
    Tanaka, Kyoko
    Hamada, Yoko
    Kasai, Midori
    Hatae, Keiko
    JOURNAL OF THE JAPANESE SOCIETY FOR FOOD SCIENCE AND TECHNOLOGY-NIPPON SHOKUHIN KAGAKU KOGAKU KAISHI, 2006, 53 (09): : 481 - 488
  • [33] AN FT-IR INVESTIGATION OF PARABACTIN ADSORBED ONTO ALUMINUM
    HANSEN, DC
    MCCAFFERTY, E
    LINS, CW
    FITZPATRICK, JJ
    APPLIED SURFACE SCIENCE, 1995, 84 (01) : 85 - 90
  • [34] FT-IR AND RAMAN INVESTIGATION OF CADMIUM BINDING BY DNA
    ALEX, S
    DUPUIS, P
    INORGANICA CHIMICA ACTA, 1989, 157 (02) : 271 - 281
  • [35] INSITU FT-IR SPECTROSCOPY OF THE ADSORPTION OF CO ON METHANOL CATALYSTS
    EDWARDS, JF
    SCHRADER, GL
    APPLIED SPECTROSCOPY, 1981, 35 (06) : 559 - 563
  • [36] Dehydration of glycerol on H-MFI zeolite investigated by FT-IR
    Yoda, Eisuke
    Ootawa, Ayako
    APPLIED CATALYSIS A-GENERAL, 2009, 360 (01) : 66 - 70
  • [37] CORROSION INVESTIGATION OF PRINTING MACHINES BY FT-IR SPECTROSCOPY
    Dragcevic, Kresimir
    Lovrecek, Mladen
    TEHNICKI VJESNIK-TECHNICAL GAZETTE, 2012, 19 (04): : 899 - 906
  • [38] Corrosion investigation of printing machines by FT-IR spectroscopy
    Dragčević, Krešimir
    Lovreček, Mladen
    Tehnicki Vjesnik, 2012, 19 (04): : 899 - 906
  • [39] FT-IR Studies of Cerium Oxide Nanoparticles and Natural Zeolite Materials
    Pop, Oana Lelia
    Diaconeasa, Zorita
    Mesaros, Amalia
    Vodnar, Dan Cristian
    Cuibus, Lucian
    Ciontea, Lelia
    Socaciu, Carmen
    BULLETIN OF UNIVERSITY OF AGRICULTURAL SCIENCES AND VETERINARY MEDICINE CLUJ-NAPOCA-FOOD SCIENCE AND TECHNOLOGY, 2015, 72 (01) : 50 - 55
  • [40] Oxidative stress effects on erythrocytes determined by FT-IR spectrometry
    Petibois, C
    Déléris, G
    ANALYST, 2004, 129 (10) : 912 - 916