Germanium analogs of carbenium ions

被引：0
|
作者：
T. A. Kochina
D. L. Myalochkin
V. V. Avrorin
E. N. Sinotova
机构：
[1] Russian Academy of Sciences,I. V. Grebenshchikov Institute of Silicate Chemistry
[2] St. Petersburg State University,Department of Chemistry
来源：
Russian Chemical Bulletin | 2016年 / 65卷
关键词：
germanium; cations of Group 14 elements; germylium cations;
D O I：
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中图分类号：
学科分类号：
摘要：
The review summarizes advances in the production of germanium analogs of carbenium ions both per se in solutions and crystals and as intermediates in reactions of organogermanium compounds. The data on the structures of germylium cations of different types are considered. Emphasis is given to the reactivity of germylium ions and their ion-molecule reactions with nucleophilic reagents in the gas and condensed phases.
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页码：597 / 620
页数：23
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