Synthesis and Crystal Structure of the π-Complex 5CuCl⋅Si(O–CH2–CH=CH2)4

被引：0

作者：

V. V. Olijnik

T. P. Korsak

V. N. Davydov

机构：

[1] Ukrainian State Wood Technology University,

[2] I. Franko Lvov State University,undefined

来源：

Journal of Structural Chemistry | 2001年 / 42卷

关键词：

Radiation; Copper; Chloride; Physical Chemistry; Crystal Structure;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

This paper discusses the results of synthesis and X-ray diffraction analysis (DARCH single crystal diffractometer, MoKα radiation) of a π-complex of copper(I) chloride with tetraallyloxysilane 5CuCl⋅Si(O–CH2–CH=CH2)4 (space group P4/n, a = 13.813(2), c = 5.9424(7) Å, Z = 2). Structural data for other olefin complexes of copper(I) are used to analyze the structural effect of the restricted disordering of the guest molecule with conservation of the high general symmetry of the structure introduced by the olefin molecule.

引用

页码：454 / 458

页数：4

共 50 条

[21] Synthesis, characterization and crystal structure of mixed quadriligand complex [Ce(CH2=C(CH3)-COO)2(NO3)(phen)]2
Zhao, SH
Xian, CY
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2002, 18 (06) : 639 - 642
[22] Synthesis and crystal structure of [C5H4C(CH3)(C2H7)CH2CH = CH2]Gd(OH)Cl•2MgCl2•4THF
Lin, J
Wang, ZY
Wang, HG
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2000, 20 (03) : 377 - 381
[23] Synthesis, structure and conductivity of the new charge-transfer salt (ET)2(CH2=CH-CH2-SO3)•H2O
Liu, Z
Fang, Q
Yu, WT
Jiang, MH
Zhang, DQ
Ben Zhu, D
CHINESE CHEMICAL LETTERS, 2003, 14 (04) : 433 - 436
[24] Copper(I) nitrate π-complexation:: Synthesis and crystal structure of [{CH2=CH-CH2-NHC(NH2)2}Cu(NO3)2] compound
Filinchuk, YE
Mys'kiv, MG
POLISH JOURNAL OF CHEMISTRY, 2000, 74 (07) : 927 - 933
[25] Bridge-splitting of trans-[PtCl2(η2-CH2=CH2)]2 by weak nucleophiles: Crystal and molecular structure of trans-[PtCl2(η2-CH2=CH2)(MeCN)]
Otto, Stefanus
Roodt, Andreas
Elding, Lars I.
INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (08) : 766 - 768
[26] Synthesis, Structure and Conductivity of the New Charge-transfer Salt （ET）2（CH2=CH-CH2-SO3）·H2O
Zhi LIU1
Chinese Chemical Letters, 2003, (04) : 433 - 436
[27] Synthesis and Crystal Structure of Copper(I) Chloride π-Complexes with N-Allyl- and N,N'-Diallylpiperazinium Dichlorides: [C3H5NH(CH2)4NH2]Cu2Cl4and [C3H5NH(CH2)4NHC3H5]0.5CuCl2
A. A. Shkurenko
V. N. Davydov
M. G. Mys'kiv
Russian Journal of Coordination Chemistry, 2003, 29 : 445 - 450
[28] Synthesis, Characterization, and Optical Properties of New Organic-Inorganic Hybrid Perovskites [(NH3)2(CH2)3]CuCl4 and [(NH3)2(CH2)4]CuCl2Br2
Abdel-Aal, Seham K.
Kandeel, Mohamed F.
El-Sherif, Ashraf F.
Abdel-Rahman, Ahmed S.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2021, 218 (12):
[29] Synthesis and crystal structure of copper(I) chloride π-complexes with N-allyl- and N,N′-diallylpiperazinium dichlorides:: [C3H5NH(CH2)4NH2]Cu2Cl4 and [C3H5NH(CH2)4NHC3H5]0.5CuCl2
Shkurenko, AA
Davydov, VN
Mys'kiv, MG
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2003, 29 (06) : 445 - 450
[30] Solvothermal synthesis and crystal structure of [H2N(CH2)2NH3]{CO[H2N(CH2)2NH2]3}[SbSe4]
Ming-Lai, F
Chen, WT
Cai, LZ
Liu, B
Guo, GC
Huang, JS
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (07) : 731 - 734

← 1 2 3 4 5 →