Basicity of {(2-amino)- and (2-aminomethyl)bicyclo[2.2.1]hept-3-yl}anilines in nitromethane

被引：0
|
作者：
I. A. Novakov
B. S. Orlinson
R. V. Brunilin
E. A. Potaenkova
E. V. Sorokina
机构：
[1] Volgograd State Technical University,
来源：
Russian Journal of General Chemistry | 2013年 / 83卷
关键词：
Aniline; Diamine; Polyimide; Nitromethane; Adamantane;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Ionization constants of {(2-amino)-bicyclo[2.2.1]-hept-3-yl}anilines and {(2-aminomethyl)bicyclo [2.2.1]-hept-3-yl}anilines in nitromethane have been determined by potentiometric titration. Due to high values of pKa 1BH+ and pKa 2BH+ (close to known adamantane-containing diamines) the studied compounds are promising candidates for preparation of (co)polyimides with a complex of excellent utilitarian properties.
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页码：2037 / 2039
页数：2
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