Parameters of electrical double layer on the boundary copper electrode/water-organic solution of copper sulfate

被引：0
|
作者：
S. M. Kuz’min
S. A. Chulovskaya
A. V. Noskov
V. I. Parfenyuk
机构：
[1] Russian Academy of Sciences,Institute of Chemistry of Solutions
来源：
Russian Journal of General Chemistry | 2009年 / 79卷
关键词：
General Chemistry; Electrical Double Layer; Copper Sulfate; Polarization Resistance; Exchange Current;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
By the method of impedance spectroscopy the properties of the phase boundary of Cu|H2O + i-C3H7OH + CuSO4 system were investigated. The impedance hodographs were obtained, in the form of circles with displaced centers. The capacity values of electrical double layer, exchange currents, and resistance of the electrolyte solution depending on the mole fraction of 2-propanol were determined. The role of organic component in the formation of the electrical double layer in the studied system is elucidated.
引用
收藏
页码：2287 / 2292
页数：5
相关论文
共 50 条
  • [1] Parameters of Electrical Double Layer on the Boundary Copper Electrode/Water-Organic Solution of Copper Sulfate
    Kuz'min, S. M.
    Chulovskaya, S. A.
    Noskov, A. V.
    Parfenyuk, V. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2009, 79 (11) : 2287 - 2292
  • [2] Stability of the Copper(II) Acetate Complexes in Water-Organic Solvents
    Isaeva, V. A.
    Sharnin, V. A.
    Shormanov, V. A.
    Shcherbina, I. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1998, 24 (02) : 139 - 141
  • [3] COMPLEXATION OF COPPER(II) WITH ETHYLENEDIAMINE IN CERTAIN WATER-ORGANIC MEDIA
    BOOS, GA
    MUSINA, SZ
    ZHURNAL NEORGANICHESKOI KHIMII, 1989, 34 (01): : 102 - 106
  • [4] Electrochemical processes on the copper electrode in water-ethanol solutions of copper sulfate
    S. M. Kuz’min
    S. A. Chulovskaya
    A. V. Balmasov
    V. I. Parfenyuk
    Russian Journal of General Chemistry, 2011, 81
  • [5] Electrochemical processes on the copper electrode in water-ethanol solutions of copper sulfate
    Kuz'min, S. M.
    Chulovskaya, S. A.
    Balmasov, A. V.
    Parfenyuk, V. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2011, 81 (03) : 463 - 469
  • [6] Optimization of copper electrowinning from synthetic copper sulfate solution using a pulsed bed electrode
    Britto-Costa, Pedro H.
    Ruotolo, Luis A. M.
    HYDROMETALLURGY, 2014, 150 : 52 - 60
  • [7] EFFECT OF THE HELMHOLTZ-GOUY DOUBLE LAYER ON THE A-C IMPEDANCE OF THE COPPER-COPPER OXIDE ELECTRODE IN AQUEOUS SOLUTION
    HOEY, GR
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1961, 108 (04) : 387 - 393
  • [8] Chemical synthesis of stable nano-sized water-organic copper dispersions
    Terskaya, I. N.
    Sal'nikov, D. S.
    Makarov, S. V.
    Yarovaya, O. V.
    Lilin, S. A.
    PROTECTION OF METALS, 2008, 44 (05): : 468 - 470
  • [9] Chemical synthesis of stable nano-sized water-organic copper dispersions
    I. N. Terskaya
    D. S. Sal’nikov
    S. V. Makarov
    O. V. Yarovaya
    S. A. Lilin
    Protection of Metals, 2008, 44 : 468 - 470
  • [10] Structure of electrical double layer at gold electrode in cyanide solution
    Rogozhnikov, N. A.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2009, 45 (07) : 725 - 730
12345