Extraction of rare-earth nitrates by phosphoryl podands

被引:0
|
作者
A. N. Turanov
V. K. Karandashev
V. E. Baulin
机构
[1] Russian Academy of Sciences,Institute of Solid State Physics
[2] Russian Academy of Sciences,Institute of Problems of Microelectronic Technology and High
[3] Russian Academy of Sciences,Purity Materials
来源
Russian Journal of Inorganic Chemistry | 2006年 / 51卷
关键词
Phosphoryl; Heavy Rare Earth; Phosphoryl Group; Extraction Ability; TPPO;
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学科分类号
摘要
The distribution of trace amounts of rare-earth nitrates between aqueous solutions of NH4NO3 and organic solutions of phosphoryl podands is studied for Ln = La, Ce, Pr, Nd, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y. The stoichiometry of the extraction complexes is determined. The effect of the structure of the extractant and the nature of the organic solvent on the efficiency of rare-earth recovery to the organic phase is considered.
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页码:1829 / 1835
页数:6
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