The spectral characteristics of chlorine-containing water clusters in the presence of ozone and oxygen

被引：0

作者：

A. E. Galashev

机构：

[1] Russian Academy of Sciences,Institute of Industrial Ecology, Ural Division

来源：

Russian Journal of Physical Chemistry A | 2009年 / 83卷

关键词：

Ozone; Raman Spectrum; Oxygen Molecule; Water Cluster; Permanent Dipole Moment;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The infrared absorption and Raman spectra were calculated by the molecular dynamics method for water clusters with chlorine ions in a medium of water and ozone or oxygen molecules. The intensity of IR absorption spectra of clusters with absorbed oxygen increased and that of clusters with absorbed ozone decreased as the number of chlorine ions grew. Excitation strengthening caused by an increase in the number of Cl− ions weakened the intensity of Raman spectra when either oxygen or ozone was absorbed; for ozone, this weakening was more noticeable.

引用

页码：2249 / 2254

页数：5

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