Synthesis of La1 − xSrxMnO3 + δ manganites by pyrohydrolysis of nitrates

被引:0
作者
E. V. Mikhaleva
V. G. Vasil’ev
A. P. Nosov
E. V. Vladimirova
B. V. Slobodin
机构
[1] Russian Academy of Sciences,Institute of Solid
[2] Russian Academy of Sciences,State Chemistry, Ural Division
来源
Glass Physics and Chemistry | 2009年 / 35卷
关键词
Lanthanum; Acrylic Acid; Manganite; Glass Physic; Metal Nitrate;
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摘要
Single-phase finely dispersed perovskite-like manganites La1 − xSrxMnO3 + δ (0 ≤ x ≤ 0.33) with an average particle size of approximately 3μm were synthesized by the pyrohydrolytic method from a stoichiometric mixture of the corresponding metal nitrates at a temperature of 500°C in a water vapor atmosphere. The parameter δ was changed as a result of the subsequent heat treatment. It was established that the manganite La0.67Sr0.33MnO3 + δ synthesized by the pyrohydrolytic method is characterized by a more pronounced change in the magnetoresistance as compared to the manganite that had the same composition but was synthesized according to the conventional ceramic technique.
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页码:81 / 86
页数:5
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