Synthesis, Characterization, Optical Properties and Theoretical Studies of Novel Substituted Imidazo[1,5-a]pyridinyl 1,3,4-Oxadiazole Derivatives

被引:0
作者
Yan-Qing Ge
Teng Wang
Gui Yun Duan
Li Hua Dong
Xiao Qun Cao
Jian Wu Wang
机构
[1] Taishan Medical University,School of Chemistry and Chemical Engineering
[2] Shandong University,undefined
来源
Journal of Fluorescence | 2012年 / 22卷
关键词
Synthesis; Oxadiazole; Imidazo[1,5-a]pyridine; Nitrogen-bridgehead; UV-vis absorption; Fluorescence;
D O I
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中图分类号
学科分类号
摘要
Novel imidazo[1,5-a]pyridinyl 1,3,4-Oxadiazole derivatives were synthesized and characterised by IR, 1H NMR and HRMS.UV-vis absorption and fluorescence properties of these compounds in different solutions showed that the maximal emission wavelength was not significantly changed in different solvents; however, maximum absorption wavelength was blue-shifted with the increase of solvent polarity. Absorption λmax and emission λmax was less correlated with substituent groups on benzene rings. The calculated molecular orbital correlates well with their absorption.
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页码:1531 / 1538
页数:7
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