We have investigated iron by EPR (electron paramagnetic resonance) and photo-EPR in initially boron doped silicon samples in which the iron concentration exceeded the boron content. A new EPR spectrum, showing orthorhombic-I symmetry was observed and could be fitted by an effective spin Hamiltonian with the parameters S=3/2, g=2.07, and E/D=0.68. We identify this spectrum as a new modification of a Fe2B center which has the same symmetry but different configuration of the constituent atoms.