Oxidation of iron with varying isotope content

被引:0
作者
Baldokhin Y.V. [1 ]
Perfiliev Y.D. [2 ]
Kulikov L.A. [2 ]
Burnazyan M.A. [2 ]
机构
[1] Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
[2] Moscow State University, Moscow
基金
俄罗斯基础研究基金会;
关键词
electron microscopy; iron; isotope content; Mössbauer spectroscopy; oxidation;
D O I
10.3103/S0027131415020030
中图分类号
学科分类号
摘要
The objective of this work is to find the features of iron oxidation with different contents of isotopes prepared in the form of foils, bulk samples, and powders. The contents of other impurity elements in pure iron samples and 57Fe iron (enrichment up to 95%) have been found to be practically identical. The oxidation products have been characterized via conversion and Auger electron Mössbauer spectroscopy, as well as via absorbed Mössbauer γ-quanta. It is noted that the natural iron foil samples with a thickness of 6.35 μm undergo air oxidation, while 57Fe isotope foil samples remain unoxidized for more than 40 years. © 2015, Allerton Press, Inc.
引用
收藏
页码:74 / 79
页数:5
相关论文
共 15 条
  • [1] Povitskii V.A., Salugin A.N., Baldokhin Y.V., Makarov E.F., Novitskii A.N., Shchukin N.F., Zashch. Met., (1977)
  • [2] Hrynkiewicz A.Z., Kulgawczuk D.S., Tomala K., Phys. Lett., (1965)
  • [3] Pustov Y.A., Baldokhin Y.V., Korrozionnostoikie i zharoprochnye materialy, (1998)
  • [4] Plachinda A.S., Chertov V.M., Suzdalev I.P., Baldokhin Y.V., Makarov E.F., Zelentsov V.I., Teor. Eksp. Khim., 10, 4, (1974)
  • [5] Baldokhin Y.V., Suzdalev I.P., Prusakov V.E., Burnazyan D.A., Korneev V.P., Kovalenko L.V., Folmanis G.E., Russ. J. Phys. Chem. B, 6, 1, pp. 81-88, (2012)
  • [6] Graham M.J., Mitchell D.F., Channing D.A., Oxid. Met., 12, 3, (1979)
  • [7] Belozerskii G., Bohm C., Ekdal T., Liljequist D., Corros. Sci., 22, 9, (1982)
  • [8] Kolotyrkin P.Y., Maksimov Y.V., Baldokhin Y.V., Krylova A.V., Dokl. Akad. Nauk SSSR, 302, 6, (1988)
  • [9] Spikerman J., Ruete F., Devaux J., in Mössbauer Effects Methodology, Groverman, I.J., et al., Eds., (1975)
  • [10] Austin J.B., Pierce R.H.H., Physics, (1933)