New acyclic aminocarbene palladium(ii) complexes as convenient catalysts for the Sonogashira and Suzuki cross-coupling

被引：0
|
作者：
E. A. Valishina
T. M. Buslaeva
K. V. Luzyanin
机构：
[1] M. V. Lomonosov Moscow State University of Fine Chemical Technologies,Department of Chemistry
[2] St.-Petersburg State University,Department of Chemistry
[3] University of Liverpool,undefined
来源：
Russian Chemical Bulletin | 2013年 / 62卷
关键词：
aminocarbene palladium complexes; metal-promoted coupling; nucleophilic addition; isocyanides; hydrazones; Sonogashira reaction; Suzuki reaction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A reaction of isocyanide complex cis-[PdCl2(CNAr)2] with hydrazones H2N-N=CR1R2 proceeded at the carbon atom of one of the isocyanide groups and gave the corresponding diaminocarbene isocyanide palladium(ii) complexes. These complexes showed high catalytic activity in the Sonogashira and Suzuki cross-coupling reactions.
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页码：1361 / 1365
页数：4
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