Electrically Conductive and Flame Retardant Graphene/Brominated Polystyrene/Maleic Anhydride Grafted High Density Polyethylene Nanocomposites with Satisfactory Mechanical Properties

被引:0
作者
Yu Chen
Jian Yao
Ming-Ke Xu
Zhi-Guo Jiang
Hao-Bin Zhang
机构
[1] Beijing Institute of Aeronautical Materials,National Key Laboratory of Advanced Composites
[2] Beijing University of Chemical Technology,Beijing Key Laboratory of Advanced Functional Polymer Composites, College of Materials Science and Engineering
来源
Chinese Journal of Polymer Science | 2019年 / 37卷
关键词
Polymer nanocomposites; High density polyethylene; Graphene; Electrical conductivity; Flame retardancy;
D O I
暂无
中图分类号
学科分类号
摘要
Electrically conductive and flame-retardant maleic anhydride grafted high-density polyethylene (MA-HDPE) nanocomposites with satisfactory mechanical properties are fabricated by melt compounding MA-HDPE with polyethyleneimine (PEI)-modified reduced graphene oxide (PEI@RGO) as the conductive nanofiller and brominated polystyrene (BPS) as the flame retardant. The modification with PEI significantly improves the interfacial compatibility and dispersion of the RGO sheets in the MA-HDPE matrix, leading to electrically conductive nanocomposites with enhanced mechanical properties. Furthermore, the addition of 25 wt% of BPS makes the nanocomposite flame-retardant with a UL-94 V-0 rating. Thus, the multifunctional RGO/MA-HDPE nanocomposites with good electrical, flameretardant, and mechanical properties would have potential applications in construction and pipeline fields.
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页码:509 / 517
页数:8
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共 229 条
[1]  
Laoutid F.(2009)New prospects in flame retardant polymer materials: From fundamentals to nanocomposites Mat. Sci. Eng. R 63 100-125
[2]  
Bonnaud L.(2017)Preparation of antistatic polystyrene superfine powder with polystyrene modified carbon nanotubes as antistatic agent Compos. Sci. Technol 138 1-7
[3]  
Alexandre M.(2013)Novel microwave–synthesis of Cu nanoparticles in the absence of any stabilizing agent and their antibacterial and antistatic applications Appl. Surf. Sci 280 610-618
[4]  
Lopez–Cuesta J. M.(2012)Processing–dependent high impact polystyrene/styrene–butadienestyrene tri–block copolymer/carbon black antistatic composites J. Appl. Polym. Sci 123 1032-1039
[5]  
Dubois P.(2014)High electrical conductive polymethylmethacrylate/graphite composites obtained via a novel pickering emulsion route J. Polym. Res 21 373-7865
[6]  
Zhang M.(2007)Effect of carbon black concentration on electrical conductivity of epoxy resin–carbon black–silica nanocomposites J. Mater. Sci 42 7861-29712
[7]  
Zhang C.(2017)Fabrication and interfacial characteristics of surface modified Ag nanoparticle based conductive composites RSC Adv 7 29702-21
[8]  
Du Z. J.(2018)Morphological, rheological and electrical properties of composites filled with carbon nanotubes functionalized with 1–pyrenebutyric acid Compos. Part B–Eng 147 12-388
[9]  
Li H. Q.(2008)Measurement of the elastic properties and intrinsic strength of monolayer graphene Science 321 385-191
[10]  
Zou W.(2007)The rise of graphene Nat. Mater 6 183-2637