Hydrothermal synthesis, crystal structural, and thermal properties of a 1D zinc coordination polymer based on benzoate and flexible bis(benzimidazole) ligands

被引：0
作者：
C. J. Wang
F. Wang
H. R. Ruo
C. C. Yang
C. H. He
G. H. Cui
机构：
[1] Hebei United University,College of Chemical Engineering
来源：
Russian Journal of Coordination Chemistry | 2013年 / 39卷
关键词：
Benzimidazole; Coordination Polymer; Empirical Absorption Correction; Benzimida Zolyl; Secondary Ligand;
D O I：
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学科分类号：
摘要：
A new coordination polymer, [Zn(PhCOO)2(Bbbm)]n (I), where Bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TG and X-ray single-crystal diffraction. The complex crystallizes in the monoclinic system with space group P21/n, the unit cell parameters: a = 10.815(3), b = 20.516(6), c = 12.802(4) Å, β = 102.025(3)°, V = 2778.2(14) Å3, Z = 4. In this structure, the Zn2+ ion is in a distorted tetrahedral geometry, one-dimensional linear chain is constructed by Bbbm ligand with bis(monodentate) coordination mode.
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页码：222 / 224
页数：2
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