Anion radical formation in the reaction of chloranilic acid with n-methylpiperidine in acetonitrile

被引：0
作者：
Miroslaw Dworniczak
机构：
[1] Adam Mickiewicz University,Faculty of Chemistry
来源：
Reaction Kinetics and Catalysis Letters | 2003年 / 78卷
关键词：
anion radical; Chloranilic acid; reaction mechanism;
D O I：
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中图分类号：
学科分类号：
摘要：
Reaction of chloranilic acid with N-methylpiperidine in acetonitrile has been studied. The product of the reaction is an unusually stable anion radical of quinone. The presence of radicals has been confirmed by EPR measurements. Stability constant, extinction coefficients and thermodynamic reaction parameters are reported. Mechanism of the reaction is proposed.
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页码：65 / 72
页数：7
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