Influence of Pyrolysis Conditions on Surface Characteristics and Methylene Blue Adsorption of Biochar Derived from Date Seed Biomass

被引:1
作者
Zainab Mahdi
Ali El Hanandeh
Qiming Yu
机构
[1] Griffith University,Environmental Futures Research Institute, Griffith School of Engineering, Nathan Campus
来源
Waste and Biomass Valorization | 2017年 / 8卷
关键词
Biochar; Date seed; Methylene blue; Adsorption; Slow pyrolysis;
D O I
暂无
中图分类号
学科分类号
摘要
Biochar samples were prepared from date seed biomass using slow pyrolysis at different temperatures (350–550 °C) and heating time (1–3 h). The influence of pyrolysis temperature and heating time on the physiochemical properties of the biochar were studied. Methylene blue (MB) adsorption by the biochar was also studied. Biochar yield decreased with increasing pyrolysis temperature and heating time. Carbon content, ash content and pH of the biochar increased with increasing pyrolysis temperature as well as heating time. FTIR analysis and scanning electron microscopy indicated that the biochars possess various surface functional groups such as carboxylic and phenolic groups. Batch adsorption results showed that the capacity of biochar to remove MB from aqueous solutions correlated positively with pyrolysis temperature and heating time. The highest MB removal capacity was achieved by the biochar prepared at 550 °C and 3 h heating time. The equilibrium results for MB adsorption on the biochar prepared at 550 °C and 3 h was well fitted to Langmuir with maximum adsorption (qmax) of 0.133 mM g−1 (42.57 mg g−1). The results suggest that date seed derived biochar can be a viable option for wastewater treatment.
引用
收藏
页码:2061 / 2073
页数:12
相关论文
共 131 条
[1]  
Ahmad M(2014)Biochar as a sorbent for contaminant management in soil and water: a review Chemosphere 99 19-33
[2]  
Rajapaksha AU(2012)Physical and chemical characteristics of activated carbon prepared by pyrolysis of chemically treated date stones and its ability to adsorb organics Powder Technol. 229 237-245
[3]  
Lim JE(2004)Mineral ion content of the seeds of six cultivars of Bahraini date palm ( J. Agric. Food Chem. 52 6522-6525
[4]  
Zhang M(2014)) Water Res. Ind. 6 1-17
[5]  
Bolan N(2010)Kinetic, equilibrium and thermodynamic investigations of Ni(II), Cd(II), Cu(II) and Co(II) adsorption on barley straw ash J. Saudi Chem. Soc. 14 47-53
[6]  
Mohan D(2013)Kinetic and equilibrium adsorption of methylene blue and remazol dyes onto steam-activated carbons developed from date pits J. Anal. Appl. Pyrol. 103 159-166
[7]  
Ok YS(1981)Production of char from hornbeam sawdust and its performance evaluation in the dye removal Am. J. Sci. 281 788-806
[8]  
Ahmed MJ(2002)The surface chemistry of goethite (alpha FeOOH) in major ion seawater Carbon 40 145-149
[9]  
Theydan SK(2008)Surface oxides on carbon and their analysis: a critical assessment J. Anal. Appl. Pyrol. 82 70-77
[10]  
Ali-Mohamed AY(2012)Preparation and characterization of activated carbon from date stones by physical activation with steam J. Anal. Appl. Pyrol. 94 215-222