Monomers for adhesive polymers1. Synthesis and radical polymerization of bicyclic monomers

被引：0
|
作者：
Norbert Moszner
Frank Zeuner
Volker Rheinberger
机构：
[1] Ivoclar AG,
来源：
Polymer Bulletin | 1997年 / 39卷
关键词：
AIBN; Maleic Anhydride; Shear Bond Strength; Butyl Acetate; Triethylene Glycol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Bicyclic functionalized methacrylates were synthesized by a Diels-Alder reaction of furfuryl methacrylate with maleic anhydride and subsequent conversion to the corresponding monomers containing carboxylic groups. The structure of the bicyclic functionalized methacrylates was confirmed by elemental analysis, 1R, 1H NMR and 13C NMR spectroscopy. The radical photopolymerization of bicyclic monomethacrylates in dimethylformamide with 2,2′azobisisobutyronitrile (AIBN) resulted in soluble polymers while a bicyclic dimethacrylate resulted in a crosslinked polymer.
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页码：669 / 676
页数：7
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