Thermochemistry of the silver(I) complexation with 18-crown-6 ether in binary acetonitrile—dimethylsulfoxide solvents

被引：0
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作者：
I. A. Kuz’mina
V. A. Sharnin
A. N. Golikov
机构：
[1] Ivanovo State University of Chemistry and Technology,
来源：
Russian Journal of Physical Chemistry A | 2012年 / 86卷
关键词：
solvation; thermodynamics; enthalpy; binary solvents; silver(I); 18-crown-6 ether;
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学科分类号：
摘要：
The effect of acetonitrile-dimethylsulfoxide solvents on the enthalpy of silver(I) complexation with 18-crown-6 ether is studied by means of calorimetry. It is found that an increase in the concentration of dimethylsulfoxide leads to an increase in the reaction exothermicity. It is shown that the determining factor in the change in the reaction enthalpy is the solvation effect of the ligand.
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页码：151 / 153
页数：2
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