Kinetics of parallel reaction between 1, 2, 4-trichlorobenzene and sodium methoxide

被引：0

作者：

Wang B. ^{[1
]}

Liu M. ^{[1
]}

Zhu J. ^{[1
]}

Jing X. ^{[1
]}

机构：

[1] Key Laboratory for Green Chemical Technology of Ministry of Education, Research and Development Center of Petrochemical Technology, Tianjin University

来源：

Transactions of Tianjin University | 2010年 / 16卷 / 03期

基金：

中国国家自然科学基金;

关键词：

1; 2; 4-trichlorobenzene; Kinetics; Liquid-solid interface reaction; Sodium methoxide; Synthesis;

D O I：

10.1007/s12209-010-0032-3

中图分类号：

学科分类号：

摘要：

Synthesis and kinetics of dichloro-methoxybenzenes were studied from 1, 2, 4-trichlorobenzene and sodium methoxide in a temperature range of 353-383 K. Effects of molar ratio of reactants, solvent and reaction temperature were investigated. Reaction products include three isomers. The order of selectivity for the three isomers was 1, 4-dichloro-2-methoxybenzene≫2, 4-dichloro-1-methoxybenzene>1, 2-dichloro-4-methoxybenzene. Kinetic equations for the parallel liquid-solid interface reaction between 1, 2, 4-trichlorobenzene and sodium methoxide were established in the absence of catalyst. Kinetic parameters such as the pre-exponential factors and the activation energy were determined with the Arrhenius equation. © Tianjin University and Springer-Verlag Berlin Heidelberg 2010.

引用

页码：174 / 178

页数：4

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