The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes

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作者：
Johannes Hohenberger
Kallol Ray
Karsten Meyer
机构：
[1] Inorganic Chemistry,Department of Chemistry and Pharmacy
[2] Friedrich-Alexander-University Erlangen – Nuremberg,Department of Chemistry
[3] Humboldt-Universität zu Berlin,undefined
来源：
Nature Communications | / 3卷
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摘要：
High-valent iron–oxo and –nitrido complexes are intermediates in the catalytic cycles of various metalloenzymes that activate dioxygen and dinitrogen. Hohenbergeret al. review the advances in the chemistry of model high-valent iron–oxo and –nitrido systems and relate them to our understanding of related enzymes.[graphic not available: see fulltext]
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