Synthesis, structure, and luminescence of the octahedral molybdenum cluster [Mo6I8(SC6F4H)6]2−

被引：0

作者：

M. N. Sokolov

M. A. Mikhailov

A. V. Virovets

K. A. Brylev

R. A. Bredikhin

A. M. Maksimov

V. E. Platonov

V. P. Fedin

机构：

[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch

[2] Novosibirsk State University,N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch

[3] Russian Academy of Sciences,undefined

来源：

Russian Chemical Bulletin | 2013年 / 62卷

关键词：

molybdenum iodides; clusters; organofluorine compounds; thiolate complexes; luminescence;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A new thiolate cluster complex (Bu4N)2[Mo6I8(SC6F4H)6] was synthesized by the metathesis reaction of (Bu4N)2[Mo6I14] and HC6F4SAg in methylene chloride. According to the X-ray structure determination, the cluster core {Mo6I8}4+ coordinates six thiolate ligands 2,3,5,6-HC6F4S−. The Mo-Mo and Mo-I distances have their usual values. The average Mo-S distance is 2.538(4) Å, and the Mo-S-C angles range from 107 to 109°. Compound (Bu4N)2[Mo6I8(SC6F4H)6] both in solid and in solution displays a bright red microsecond luminescence, which is typical of octahedral molybdenum halide complexes.

引用

页码：1764 / 1767

页数：3

共 50 条

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