Phosphine-catalyzed [3+2] cycloaddition of Morita—Baylis—Hillman carbonates to isothiocyanates in the synthesis of adamantane-containing trisubstituted aminothiophenes

被引：0

作者：

I. S. Zenkov

A. S. Abel

A. D. Averin

G. M. Butov

I. P. Beletskaya

机构：

[1] Lomonosov Moscow State University,Department of Chemistry

[2] Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences,undefined

[3] Volzhsky Polytechnic Institute (branch) of Volgograd State Technical University,undefined

来源：

Russian Chemical Bulletin | 2021年 / 70卷

关键词：

thiophene; organocatalysts; phosphines; adamantane; isothiocyanates; Morita—Baylis—Hillman carbonates;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

An addition of the Morita—Baylis—Hillman (MBH) carbonates to adamantane-containing isothiocyanates was studied. The MBH carbonates react with 1-(4-isothiocyanatophenyl)-adamantane in the presence of triphenylphosphine to give 5-aryl-substituted adamantane-containing 2-amino-4-methoxycarbonylthiophenes in 31–59% yields, while 1- and 2-isothio-cyanatoadamantanes were found unreactive in this reaction.

引用

页码：880 / 884

页数：4

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