Partial molar volume of dodecyltrimethylammonium hydroxide in water and NaOH aqueous solutions

被引:0
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作者
M. A. Morini
R. M. Minardi
P. C. Schulz
J. E. Puig
J. L. Rodriguez
机构
[1] Departamento de Química e Ingeniería Universidad Nacional del Sur Avda. Alem 1253 8000 Bahía Blanca Argentina,
[2] Departamento de Ingeniería Química Universidad de Guadalajara Jal. México,undefined
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Key words Hydroxide surfactants; micelles; partial molar volume; Dodecyltrimethylammonium hydroxide;
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摘要
 The partial molar volume of dodecyltrimethylammonium hydroxide in water and aqueous NaOH solutions was measured. The addition of NaOH did not affect either the micellized or the unmicellized molecules. The expansion on micellization is much larger than in dodecyltrimethylammonium bromide systems, which reflects the stronger ionization of the hydroxide surfactant micelles, when compared with that of the bromide amphiphile.
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页码:738 / 742
页数:4
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