Synthesis, crystal structure, and characterizations of a (6,3)-connected coordination polymer based on cadmium(II) and nickel(II)

被引:0
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作者
Z. H. Meng
Z. G. Zhong
X. X. Wang
J. L. Zhao
机构
[1] Nanyang Normal University,College of Chemistry and Pharmacy Engineering
[2] Nanyang Normal University,Center of Analytical and Testing
[3] Hebei University of Technology,School of Material Science and Engineering
[4] Hebei University of Technology,School of Chemical Engineering and Technology
关键词
Energy Dispersive Spectroscopy; Coordination Chemistry; Energy Dispersive Spectroscopy Analysis; Energy Dispersive Spectroscopy Result; Distorted Octahedral Coordination Geometry;
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摘要
A novel heteronuclear coordination polymer Cd(1,3-μ-SCN)6Ni2(C2H8N2)2(H2O)2 (I) has been prepared and characterized by elemental analysis, EDS analysis, PXRD and IR spectrum and single-crystal X-ray diffraction. The single-crystal X-ray diffraction analysis revealed that compound I crystallizes in a monoclinic system of space group C2/m with a = 19.427(8), b = 9.622(3), c = 7.261(3) Å, β = 105.383(10)°. The compound exhibits a (6,3)-connected two-dimensional layer which is built up from the strict alternation of 6-connected {CdS6} octahedra and 3-connected {NiON5} octahedra.
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页码:63 / 67
页数:4
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