Oxidative dimerization of 2,6-Di-tert-butyl-4-(2-hydroxyethyl)phenol

被引：0
|
作者：
A. P. Krysin
A. M. Genaev
L. M. Pokrovskii
M. M. Shakirov
机构：
[1] Russian Academy of Sciences,Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
来源：
Russian Journal of Organic Chemistry | 2014年 / 50卷
关键词：
Petroleum Ether; Oxidative Transformation; Potassium Hexacyanoferrate; Oxidative Dimerization; Butylphenol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
2,6-Di-tert-butyl-4-(2-hydroxyethyl)phenol undergoes oxidative self-coupling by the action of K3Fe(CN)6 in alkaline medium at room temperature to give 7,9-di-tert-butyl-4-(3,5-di-tert-butyl-4-hydroxyphenyl)-1-hydroxymethyl-2-oxaspiro[4.5]deca-6,9-dien-8-one. The composition of the reaction products has been determined, and the mechanism of their formation is discussed.
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页码：367 / 370
页数：3
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