Molar heat capacity and thermodynamic properties of crystalline Eu(C2H5O2N)2Cl3·3H2O

被引：0
|
作者：
X.-C. Lv
Z.-C. Tan
X.-H. Gao
L.-X. Sun
机构：
[1] Liaoning Shihua University,School of Chemistry and Material Science
[2] Dalian Institute of Chemical Physics,Division of Energy Storage, Dalian National Laboratory for Clean Energy Laboratory
[3] Chinese Academy of Sciences,Thermochemistry Laboratory
[4] Dalian Institute of Chemical Physics,Materials and Thermochemistry Laboratory
[5] Chinese Academy of Sciences,undefined
[6] Dalian Institute of Chemical Physics,undefined
[7] Chinese Academy of Sciences,undefined
来源：
Journal of Thermal Analysis and Calorimetry | 2013年 / 113卷
关键词：
Eu(C; H; O; N); Cl; ·3H; O; Adiabatic calorimetry; Low-temperature heat capacity; Thermal analysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A complex of europium hydrochloric acid coordinated with 2-aminoacetic acid (C2H5O2N), Eu(C2H5O2N)2Cl3·3H2O was synthesized and characterized by IR and elements analysis. The heat capacities of the complex was measured with an automatic adiabatic calorimeter, and the thermodynamic functions [HT − H298.15] and [ST − S298.15] were derived in the temperature range from 80 to 340 K with temperature interval of 5 K. Thermal decomposition behavior of the complex in nitrogen atmosphere was studied by thermogravimetric (TG) analysis and differential scan calorimeter (DSC).
引用
收藏
页码：971 / 976
页数：5
相关论文
共 50 条
  • [1] Molar heat capacity and thermodynamic properties of crystalline Eu(C2H5O2N)2Cl3•3H2O
    Lv, X. -C.
    Tan, Z. -C.
    Gao, X. -H.
    Sun, L. -X.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 113 (02) : 971 - 976
  • [2] Thermodynamic Properties of Nd(Gly)2Cl3•3H2O and Pr(Ala)3Cl3•3H2O
    Liu Bei-Ping
    Tan Zhi-Cheng
    ACTA PHYSICO-CHIMICA SINICA, 2013, 29 (01) : 17 - 22
  • [3] Low-Temperature Heat Capacity and Thermodynamic Functions of Ho(NO3)3(C2H5O2N)4•H2O
    Gao Xiao-Han
    Xu Pei
    Duan Wen-Chao
    Lu Xue-Chuan
    Tan Zhi-Cheng
    Lu Qiang
    ACTA PHYSICO-CHIMICA SINICA, 2013, 29 (10) : 2123 - 2128
  • [4] Molar heat capacity and thermodynamic properties of crystalline [Nd(Glu)(H2O)5(Im)3](ClO4)6·2H2O
    X. -C. Lv
    Z. -C. Tan
    X. -H. Gao
    Q. Shi
    L. -X. Sun
    Journal of Thermal Analysis and Calorimetry, 2009, 95 : 387 - 392
  • [5] Molar heat capacity and thermodynamic properties of crystalline Ho(Asp)Cl2·6H2O
    B. P. Liu
    X. C. Lv
    Z. C. Tan
    Z. H. Zhang
    Q. Shi
    L. N. Yang
    J. Xing
    L. X. Sun
    T. Zhang
    Journal of Thermal Analysis and Calorimetry, 2007, 89 : 283 - 287
  • [6] Molar heat capacity and thermodynamic properties of Lu(C5H9NO4)(C3H4N2)6(ClO4)3·5HClO4·10H2O
    X.-C. Lv
    Z.-C. Tan
    X.-H. Gao
    P. Chen
    Journal of Thermal Analysis and Calorimetry, 2013, 111 : 971 - 976
  • [7] Molar heat capacity and thermodynamic properties of crystalline [Nd(Glu)(H2O)5(Im)3](ClO4)6•2H2O
    Lv, X.-C.
    Tan, Z.-C.
    Gao, X.-H.
    Shi, Q.
    Sun, L.-X.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 95 (02) : 387 - 392
  • [8] Molar heat capacity and thermodynamic properties of crystalline Ho(Asp)Cl2•6H2O
    Liu, B. P.
    Lv, X. C.
    Tan, Z. C.
    Zhang, Z. H.
    Shi, Q.
    Yang, L. N.
    Xing, J.
    Sun, L. X.
    Zhang, T.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2007, 89 (01) : 283 - 287
  • [9] Molar heat capacity and thermodynamic properties of Lu(C5H9NO4)(C3H4N2)6(ClO4)3•5HClO4•10H2O
    Lv, X. -C.
    Tan, Z. -C.
    Gao, X. -H.
    Chen, P.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 111 (01) : 971 - 976
  • [10] Heat capacity and thermodynamic properties of ethyl carbazate (C3H8N2O2)
    Di, YY
    Sun, XH
    Tan, ZC
    Liu, YF
    Meng, SH
    Gao, SL
    Qu, SS
    THERMOCHIMICA ACTA, 2001, 369 (1-2) : 25 - 30
12345