MOF-Derived CoSe2@N-Doped Carbon Matrix Confined in Hollow Mesoporous Carbon Nanospheres as High-Performance Anodes for Potassium-Ion Batteries

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作者
Su Hyun Yang
Seung-Keun Park
Yun Chan Kang
机构
[1] Korea University,Department of Materials Science and Engineering
[2] Kongju National University,Department of Chemical Engineering
来源
Nano-Micro Letters | 2021年 / 13卷
关键词
Metal–organic frameworks; Hollow mesoporous carbon nanospheres; Potassium-ion batteries; Cobalt selenides; Electrode materials;
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摘要
A novel vacuum-assisted strategy is proposed to form N-doped carbon-encapsulated CoSe2 nanocrystals within hollow mesoporous carbon nanospheres (CoSe2@NC/HMCS) via a solid-state reaction.The “dual confinement” by both the N-doped carbon matrix derived from 2-methylimidazole and the small-sized pores of the hollow mesoporous carbon nanospheres can effectively prevent the overgrowth of CoSe2 nanocrystals.CoSe2@NC/HMCS exhibits an excellent electrochemical performance as the anode material for KIBs in terms of cycling stability and rate capability.
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