Synthesis and Crystal Structure of the Octametallic Ferrocene Containing Molybdenum(V) Cluster Mo4(μ3-O)4(μ2-O2P(CH2)2Fc)4O4 and Crystal Structure of 1,1′-Bis(Chloromethyl)Ferrocene

被引：0

作者：

John S. Maass

Matthias Zeller

Rudy L. Luck

机构：

[1] Michigan Technological University,Department of Chemistry

[2] Youngstown State University,Department of Chemistry

来源：

Journal of Cluster Science | 2012年 / 23卷

关键词：

Molybdenum tetramer; Distorted cube; Organophosphinic acid; X-ray diffraction; Ferrocene;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The reaction of MoO2(acac)2 with 1,1′-[phosphinicobis(methylene)]-ferrocene in ethanol at 120 °C and in the presence of triethylamine results in the octametallic cluster Mo4(μ3-O)4(μ2-O2P(CH2)2Fc)4O4. If the reaction is carried out in the absence of triethylamine a mixture of products are obtained of which the identity of the compound produced was hypothesized but not definitively established. Mo4(μ3-O)4(μ2-O2P(CH2)2Fc)4O4 is characterized by IR and 31P-NMR spectroscopy along with the single crystal X-ray determination of its structure. The crystal structure of 1,1′-bis(chloromethyl)ferrocene is also detailed.

引用

页码：713 / 726

页数：13

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