N-Chloro-N-(1,2,2,2-tetrachloro- and 1,2,2-trichloroethyl)- sulfonamides from N,N-Dichlorosulfonamides and 1,2-Polychloroethenes

被引:0
作者
E. V. Kondrashov
I. B. Rozentsveig
G. G. Levkovskaya
L. V. Kanitskaya
机构
[1] Favorskii Irkutsk Institute of Chemistry,
[2] Siberian Division,undefined
[3] Russian Academy of Sciences,undefined
来源
Russian Journal of Organic Chemistry | 2003年 / 39卷
关键词
Sulfonamide; Organic Chemistry; Chlorine; Trichloroethylene; Addition Product;
D O I
暂无
中图分类号
学科分类号
摘要
N,N-Dichlorosulfonamides react with trichloroethylene and 1,2-dichloroethylene at a temperature not exceeding 20°C to afford unstable addition products, N-chloro-N-(1,2,2,2-tetrachloroethyl)- and N-chloro-N-(1,2,2-trichloroethyl)sulfonamides. The latter undergo elimination of chlorine on heating, irradiation, or prolonged storage to give the corresponding N-(2,2-di- or 2,2,2-trichloroethylidene)arene(or trifluoromethane)sulfonamides.
引用
收藏
页码:1418 / 1420
页数:2
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