Effects of solvents and Sb sources on the morphologies of LaFe3CoSb12 nanopowders made by the hydro/solvo thermal method

被引：7

作者：

Lu, Pengxian ^{[1
,2
,3
]}

Shen, Zigang ^{[1
,2
]}

Hu, Xing ^{[1
,2
]}

机构：

[1] Zhengzhou Univ, Sch Phys Engn, Zhengzhou 450045, Peoples R China

[2] Zhengzhou Univ, Phys Mat Lab, Zhengzhou 450045, Peoples R China

[3] Henan Univ Technol, Coll Mat Sci & Engn, Zhengzhou 450007, Peoples R China

来源：

JOURNAL OF MATERIALS RESEARCH | 2009年 / 24卷 / 09期

关键词：

THERMOELECTRIC PROPERTIES; SKUTTERUDITES; NANOTUBES; DEVICES; ALLOYS; ROUTE; MERIT;

D O I：

10.1557/JMR.2009.0363

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The thermoelectric LaFe3CoSb12 nanopowders were synthesized by the hydro/solvo thermal method. The effects of different solvents were investigated by using only the potassium antimony tartrate as Sb source. Also, the effects of the different Sb sources were investigated by using only water as solvent on the morphologies of the resulting nanopowders. The results show that a mixture of nanoparticles and nanorods can be obtained in aqueous solution of cetyltrimethylammonium bromide or ethylenediamine-tetra-acetic disodiurn salt. In ethylenediamine only nanorods can be obtained, and in ethylene glycol only nanoparticles can be obtained. The other morphologies of the LaFe3CoSb12, such as particle-like, nest-shaped, branch-shaped, or feather-like crystalline, can be synthesized in water by selecting a suitable Sb source.

引用

页码：2873 / 2879

页数：7

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