Crystal structure of K2[Mo3(PdPPh3)S4(C2O4)3(H2O)3]·0.5H2O

被引:0
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作者
A. L. Gushchin
M. N. Sokolov
D. Yu. Naumov
V. P. Fedin
机构
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
来源
Journal of Structural Chemistry | 2008年 / 49卷
关键词
molybdenum; palladium; chalcogenide clusters; cuboidal clusters; X-ray analysis;
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学科分类号
摘要
By the reaction of [Mo3S4(C2O4)3(H2O)3]2− with PdCl2 and NH4H2PO2 as a reducing agent, followed by the addition of PPh3, a new oxalate cuboidal cluster complex [Mo3(PdPPh3)S4(C2O4)3(H2O)3]2− is obtained. It was isolated and structurally characterized as K2[Mo3(PdPPh3)S4(C2O4)3(H2O)3]·0.5H2O.
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页码:748 / 752
页数:4
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