Spherical and cylindrical inert electrode/solid electrolyte interface charging kinetics

The inert electrode/solid electrolyte interface charging kinetics in the cases of spherical and cylindrical electrode was studied by the operation impedance method in two modes (pulse galvanostatic and pulse potentiostatic). The considered case of slow diffusion and adsorption-desorption of the minor carriers (rigid sublattice defects) of solid electrolyte is true for relatively long charging time of the studied interface. The comparative analysis involved the derived potential-time and current-time kinetic relationships and similar earlier expressions for plane inert electrode.