Pulsed field gradient NMR diffusion measurement in nanoporous materials

Labeling in diffusion measurements by pulsed field gradient (PFG) NMR is based on the observation of the phase of nuclear spins acquired in a constant magnetic field with purposefully superimposed field gradients. This labeling does in no way affect microdynamics and provides information about the probability distribution of molecular displacements as a function of time. An introduction of the measuring principle is followed by a detailed description of the ranges of measurements and their limitation. Particular emphasis is given to an explanation of possible pitfalls in the measurements and the ways to circumvent them. Showcases presented for illustrating the wealth of information provided by PFG NMR include a survey on the various patterns of concentration dependence of intra-particle diffusion and examples of transport inhibition by additional transport resistances within the nanoporous particles and on their external surface. The latter information is attained by combination with the outcome of tracer exchange experiments, which are shown to become possible via a special formalism of PFG NMR data analysis. Further evidence provided by PFG NMR concerns diffusion enhancement in pore hierarchies, diffusion anisotropy and the impact of diffusion on chemical conversion in porous catalysts. A compilation of the specifics of PFG NMR and of the parallels with other measurement techniques concludes the paper.