Alkylation of furancarboxylic acid derivatives with alkenes catalyzed by nickel complexes with N-heterocyclic carbenes

被引：0
作者：
K. E. Shepelenko
S. B. Soliev
K. A. Nikolaeva
M. E. Minyaev
V. M. Chernyshev
机构：
[1] M. I. Platov South-Russian State Polytechnic University (NPI),N. D. Zelinsky Institute of Organic Chemistry
[2] Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2023年 / 72卷
关键词：
nickel; furans; N-heterocyclic carbenes; CH-alkylation; catalysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
An efficient catalytic system based on commercially available nickel source (NiCp2), N-heterocyclic carbene, and a reducing agent (HCOONa) for selective C(5)H-alkylation of amides and esters of 2-furancarboxylic acid with alkenes of various structures was developed. A series of new previously undescribed 5-alkyl derivatives of 2-furancarboxylic acid were synthesized.
引用
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页码：1746 / 1752
页数：6
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