Synthesis, characterization and catalytic epoxidation of cyclohexene using dimeric cis-dioxomolybdenum(VI) bis-bidentate Schiff base complexes supported on single wall carbon nanotubes

被引：0
作者：
Masoud Salavati-Niasari
Mehdi Bazarganipour
机构：
[1] University of Kashan,Institute of Nano Science and Nano Technology
[2] University of Kashan,Department of Chemistry, Faculty of Science
来源：
Transition Metal Chemistry | 2008年 / 33卷
关键词：
Schiff Base; Naphthyl; TBHP; Schiff Base Ligand; Aminophenyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Three dimeric cis-dioxomolybdenum(VI) complexes of bis-bidentate Schiff base derivatives containing aromatic nitrogen–nitrogen linkers (4,4′-diaminodiphenylmethane; 4,4′-diaminodiphenylether; 4,4′-diaminodiphenylsulfone) with 2-hydroxy-1-naphthaldehyde have been synthesised and characterized by physico-chemical and spectroscopic methods. The catalytic activities of the complexes with respect to alkene epoxidation using tert-butylhydroperoxide (TBHP) as oxidant have been studied. The addition of single wall nanotubes can enhance the catalytic activities of the Mo complexes and the selectivity of epoxide formation.
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页码：751 / 757
页数：6
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