Isodiagonality in the periodic table

被引：2
作者：
Rayner-Canham G. [1 ]
机构：
[1] Grenfell Campus, Memorial University, Corner Brook, NL
来源：
Foundations of Chemistry | 2011年 / 13卷 / 2期
关键词：
Diagonal relationship; Isodiagonality; Periodic patterns; Periodic table;
D O I：
10.1007/s10698-011-9108-y
中图分类号：
学科分类号：
摘要：
Diagonal relationships in the periodic table were recognized by both Mendeléev and Newlands. More appropriately called isodiagonal relationships, the same three examples of lithium with magnesium, beryllium with aluminum, and boron with silicon, are commonly cited. Here, these three pairs of elements are discussed in detail, together with evidence of isodiagonal linkages elsewhere in the periodic table. General criteria for defining isodiagonality are proposed. © 2011 Springer Science+Business Media B.V.
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页码：121 / 129
页数：8
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共 29 条
  • [1] Sandwich molecule defies theory, New Sci., 28, (1987)
  • [2] Brown T.M., Dronsfield A.T., Ellis P.M., Li-Mg: a life-saving relationship, Educ. Chem., 34, pp. 72-74, (1997)
  • [3] Cartledge G.H., Studies on the periodic system. II the ionic potential and related properties, J. Amer. Chem. Soc., 50, pp. 2863-2872, (1928)
  • [4] Dillon K.B., Mathey F., Nixon J.F., Phosphorus: The Carbon Copy: From Organophosphorus to Phospha-Organic Chemistry, (1998)
  • [5] Dyker C.A., Burford N., Catena-phosphorus cations, Chem. Asian J, 3, pp. 28-36, (2008)
  • [6] Edwards P.P., Sienko M.J., On the occurrence of metallic character in the periodic table of elements, J. Chem. Educ., 60, pp. 691-696, (1983)
  • [7] Gimarc B.M., Warren D.S., Molecular structures, stabilities, and electronic states of the planar rings S<sub>3</sub>N<sub>2</sub><sup>+</sup> and S<sub>3</sub>N<sub>2</sub><sup>2+</sup>, Inorg. Chem., 30, pp. 3276-3280, (1991)
  • [8] Greenwood N.N., Earnshaw A., Chemistry of the Elements, (1997)
  • [9] Habashi F., A new look at the periodic table, Interdiscip. Sci. Rev., 12, pp. 53-60, (1997)
  • [10] Hanusa T.P., Reexamining the diagonal relationships, J. Chem. Educ., 64, pp. 686-687, (1987)
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