Supramolecular assembly based on a heteropolyanion: Synthesis and crystal structure of Na3(H2O)6[Al(OH)6Mo6O18]·2H2O

被引：0
作者：
Vaddypally Shivaiah
Samar K. Das
机构：
[1] University of Hyderabad,School of Chemistry
来源：
Journal of Chemical Sciences | 2005年 / 117卷
关键词：
Anderson-type heteropolyanions; sodium cation as linkers; three-dimensional network structure; guest supramolecular water dimers; hydrogen-bonding interactions;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Synthesis and structural characterization of a polyoxometalate compound Na3(H2O)6 [Al(OH)6Mo6O18]-2H2O (1) have been described. Compound1 exhibits three-dimensional network structure in the solid state, which is assembled by Anderson-type heteropolyanions, [Al(OH)6Mo6O18]n3n-, as building blocks sharing sodium cations.1 possesses “sinuous” channels occupied by supramolecular water dimers as guests. Anderson anions, sodium-coordinated water and crystal water are additionally involved in an intricate hydrogen-bonding network in the crystal of1.
引用
收藏
页码：227 / 233
页数：6
相关论文
共 86 条
[1]  
Hagrman P J(1999)undefined Angew. Chem., Int. Ed. Engl. 38 2638-2638
[2]  
Hagrman D(1999)undefined Angew. Chem., Int. Ed. Engl. 38 3268-3268
[3]  
Zubieta J(1998)undefined Acc. Chem. Res. 31 474-474
[4]  
Cheetham A K(2000)undefined Angew. Chem., Int. Ed. Engl. 39 3052-3052
[5]  
Ferey G(1997)undefined Angew. Chem., Int. Ed. Engl. 36 1431-1431
[6]  
Loiseau T(1999)undefined Science 283 1125-1125
[7]  
Richardson D(1999)undefined Science 283 1145-1145
[8]  
Groy T L(1997)undefined Chem. Eur. J. 3 1745-1745
[9]  
Zaworotko M J(2001)undefined Inorg. Chem. 40 3237-3237
[10]  
Janiak C(2000)undefined Inorg. Chem. 39 4174-4174
123456789