Combustion synthesis of compounds in the Y 2O 3-Al 2O 3 system

被引:13
作者
P. Yadav
A. A. Muley
C. P. Joshi
S. V. Moharil
P. L. Muthal
S. M. Dhopte
机构
[1] Physics Department, Shri Ramdeobaba KN Engineering College, Nagpur, 440013, Katol Road
[2] Department of Physics, RTM Nagpur University, Nagpur
[3] National Environmental Engineering Research Institute, CSIR, Nagpur
关键词
Ce [!sup]3+[!/sup; Combustion synthesis; Luminescence; Phosphors; YAG; YAP;
D O I
10.3103/S1061386212020124
中图分类号
学科分类号
摘要
In the Y 2O 3-Al 2O 3 system, compounds Y 3Al 5O 12 (yttrium aluminum garnet, YAG), YAlO 3 (yttrium aluminum perovskite, YAP), and Y 4Al 2O 9 (yttrium aluminate monoclinic, YAM) are well known. YAG and YAP are of considerable technological importance. Conventional solid-state reaction techniques require high sintering temperatures (above 1800°C) to prepare phase-pure compounds. Though several soft chemical routes have been explored for synthesis of YAG, YAP and YAM, most of these methods are complex. Moreover, phase-pure materials are not obtained in one step and prolonged annealing at temperatures around 1000°C is necessary. In this paper, one-step combustion synthesis of these compounds is reported using a modified procedure and employing mixed (glycine + urea) fuel. Phosphors based on Ce 3+ activation were also prepared and exhibited characteristic photoluminescence. © Allerton Press, Inc., 2012.
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页码:124 / 133
页数:9
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