Azamacrocyclic nickel(II) and copper(II) complexes bearing aryl substituents: synthesis, properties, and crystal structures

被引：0
作者：
L. V. Tsymbal
I. L. Andriichuk
Ya. D. Lampeka
H. Pritzkow
机构：
[1] National Academy of Sciences of the Ukraine,L. V. Pisarzhevskii Institute of Physical Chemistry
[2] Universität Heidelberg,undefined
[3] Anorganisch-Chemisches Institut,undefined
来源：
Russian Chemical Bulletin | 2010年 / 59卷
关键词：
Key words; nickel(II); copper(II); azamacrocyclic complexes; absorption spectra; redox properties; X-ray diffraction analysis.;
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摘要：
A synthetic procedure for preparation of new amphiphilic copper(II) and nickel(II) azamacrocyclic complexes bearing aromatic substituents is developed. The nature of substituents is shown to exert a negligible influence on spectral and electrochemical characteristics of the prepared compounds. The X-ray diffraction analysis of three copper complexes revealed the formation of the dimers of macrocyclic cations associated by noncovalent interactions, nature of which is determined by the structure of the substituent in the macrocyclic ligand.
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页码：1572 / 1581
页数：9
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