Dipolar and Scalar Couplings in Solid State NMR of Quadrupolar Nuclei

被引：0
|
作者：
Alexej Jerschow
机构：
[1] Department of Chemistry,
[2] New York University,undefined
[3] New York,undefined
[4] NY 10003,undefined
来源：
Monatshefte für Chemie / Chemical Monthly | 2002年 / 133卷
关键词：
Keywords. Solid-state; NMR spectroscopy; Dipolar couplings; Quadrupolar couplings.;
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学科分类号：
摘要：
 Most NMR-active nuclei found in the periodic table have a quadrupole moment. In combination with a nonsymmetric electron distribution a strong NMR-active interaction results, which very often overshadows the dipolar and scalar couplings. This article aims at reviewing how these interactions manifest themselves in quadrupolar NMR and how they can be exploited for resonance assignment and structure elucidation, in spite of the presence of a strong quadrupolar interaction.
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页码：1481 / 1496
页数：15
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