Hydroisomerization of benzene-containing gasoline fractions on Pt/-ZrO 2-4Al2O3 Catalyst: Conversion of model and real feedstocks

被引:2
作者
Kazakov M.O. [1 ]
Lavrenov A.V. [1 ]
Duplyakin V.K. [1 ]
机构
[1] Institute of Problems of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, Omsk
关键词
Benzene concentration reduction; Hydroisomerization; Sulfated zirconia;
D O I
10.1134/S2070050413030057
中图分类号
学科分类号
摘要
The conversion of benzene-containing gasoline fractions on the bifunctional Pt/ - ZrO2-4Al2O3 catalytic system with different compositions of the support is studied. Using the results from hydroisomeriza- tion of a heptane-benzene model mixture, it is shown that a system with 67.8 wt % of aluminum oxide in its support has the best catalytic properties. For the IBP-85°C industrial benzene-containing fraction (23.7 wt % of benzene), it is established that the given catalyst ensures the complete removal of arenes from the benzene- containing fraction while raising its research octane number by 2.2-3.3 points and retaining a high yield of liquid products at levels of 98.7 wt % and higher. © Pleiades Publishing, Ltd., 2013.
引用
收藏
页码:209 / 215
页数:6
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