Asymmetric Henry reaction catalyzed by oxazolinyl Cu(II) complexes

被引：0
|
作者：
Luo Mei
Yin Hao
Zhang Jia Hai
Hu Ke Liang
Pang Wen Min
机构：
[1] Hefei University of Technology,Department of Chemical Engineering
[2] University of Science and Technology of China,undefined
来源：
Research on Chemical Intermediates | 2009年 / 35卷
关键词：
Oxazolinyl copper(II) catalysts; Lewis acid catalysts; Henry reaction; Nitroalcohol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel family of oxazolinyl copper(II) catalysts have been developed and used as Lewis acid catalysts in the asymmetric Henry reaction of various aldehydes with nitromethane. The corresponding nitroalcohol products were obtained in moderate yields (40–80%) and with moderate enantioselectivity (10–40% ee).
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页码：123 / 136
页数：13
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