Applications of nuclear magnetic resonance to study the structure of platinum-group metal complexes in aqueous solutions

被引：0
|
作者：
M. A. Fedotov
机构：
[1] Russian Academy of Sciences,Boreskov Institute of Catalysis, Siberian Branch
来源：
Journal of Structural Chemistry | 2016年 / 57卷
关键词：
Ru; Rh; Pd; Os; Pt NMR; platinum metal complexes; aqueous solutions; coordinate shift; inorganic ligands; amino acid ligands; radioactive waste;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The review includes comprehensive NMR data on platinum metals (99,101Ru, 103Rh, 105Pd, 187Os, 195Pt) and ligand donor atoms (1H, 13C, 14,15N, 17O, 19F, 31P) of metal complexes in aqueous solutions. A systematic analysis of NMR spectroscopy techniques is presented with focus on the measurements of NMR parameters in these systems. A novel concept referred to as coordinate shift is introduced, allowing interpretation of NMR spectra of platinum metal complexes. The review contains an encyclopedic NMR database covering a period of over 50 years from the first measured NMR spectra of platinum metals to 2014.
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页码：563 / 613
页数：50
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