Density and surface tension polytherms of gallium-lead melts

被引:0
|
作者
V. P. Chentsov
A. G. Mozgovoi
V. G. Shevchenko
A. I. Kiselev
机构
[1] Russian Academy of Sciences,Institute of Metallurgy, Ural Branch
[2] Russian Academy of Sciences (IVTAN),Joint Institute for High Temperatures
[3] Russian Academy of Sciences,Institute of Chemistry of Solids, Ural Branch
来源
High Temperature | 2012年 / 50卷
关键词
Surface Tension; Gallium; Atomic Volume; Excess Entropy; Primary Interaction;
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摘要
The density and surface tension of gallium-lead melts have been determined using the sessile drop technique in the temperature range of 600–1000°C. According to the form of polytherms of surface tension of a system with Ga-Pb exfoliation, a conclusion was made about the primary distribution of lead ions on the melt-vapor boundary. The excess entropies of melt formation were calculated. The comparison of experimental and calculated values of excess entropies showed that primary interaction between similar ions highlights the linear character of density polytherms.
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页码:38 / 43
页数:5
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