Synthesis, extraction, and chromatographic purification of higher empty fullerenes and endohedral gadolinium metallofullerenes

被引：0
|
作者：
V. S. Kozlov
M. V. Suyasova
V. T. Lebedev
机构：
[1] National Research Center Kurchatov Institute,Konstantinov Petersburg Institute of Nuclear Physics
来源：
Russian Journal of Applied Chemistry | 2014年 / 87卷
关键词：
Fullerene; Fullerene Molecule; Fullerene Cage; Gadolinium Oxide; High Fullerene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Higher empty and endohedral gadolinium metallofullerenes were prepared by electric arc synthesis, isolated, and separated chromatographically to high degree of purity (99 wt %). The samples obtained were characterized by chromatography, optical spectroscopy, and mass spectrometry. According to small-angle neutron scattering data, the endohedral metallofullerenes in o-xylene form a molecular solution in which the molecules interact to form molecular pairs.
引用
收藏
页码：121 / 127
页数：6
相关论文
共 23 条
  • [1] Synthesis, extraction, and chromatographic purification of higher empty fullerenes and endohedral gadolinium metallofullerenes
    1600, Izdatel'stvo Nauka (87):
  • [2] Synthesis, extraction, and chromatographic purification of higher empty fullerenes and endohedral gadolinium metallofullerenes
    Kozlov, V. S.
    Suyasova, M. V.
    Lebedev, V. T.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2014, 87 (02) : 121 - 127
  • [3] A study of the synthesis of endohedral metallofullerenes and empty fullerenes by the carbon-arc and RFICP technique
    Tran, NE
    Lagowski, JJ
    CARBON, 2002, 40 (06) : 939 - 948
  • [4] Supramolecular Purification and Regioselective Functionalization of Fullerenes and Endohedral Metallofullerenes
    Fuertes-Espinosa, Carles
    Pujals, Miriam
    Ribas, Xavi
    CHEM, 2020, 6 (12): : 3219 - 3262
  • [5] Non-Chromatographic Purification of Endohedral Metallofullerenes
    Wang, Zhiyong
    Omachi, Haruka
    Shinohara, Hisanori
    MOLECULES, 2017, 22 (05):
  • [6] Photophysical and photochemical properties of higher fullerenes and endohedral metallofullerenes
    Ito, O
    Fujitsuka, M
    Akasaka, T
    Yamamoto, K
    NANONETWORK MATERIALS: FULLERENES, NANOTUBES AND RELATED SYSTEMS, 2001, 590 : 489 - 492
  • [7] Surface-induced fragmentation of higher fullerenes and endohedral metallofullerenes
    Kimura, T
    Sugai, T
    Shinohara, H
    JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (19): : 9681 - 9687
  • [8] Synthesis of High Yield of Higher Endohedral Metallofullerenes
    Li Nan
    Liu Jia
    Shi Zu-Jin
    Xu Shu-Kun
    Gu Zhen-Nan
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2009, 30 (07): : 1284 - 1286
  • [9] Yttrium-containing endohedral metallofullerenes: Synthesis and extraction
    Churilov, G. N.
    Vnukova, N. G.
    Tomashevich, E. V.
    Dudnik, A. I.
    Glushchenko, G. A.
    Dubinina, I. A.
    Gulyaeva, U. E.
    Mel'nikova, E. I.
    PHYSICS OF THE SOLID STATE, 2017, 59 (08) : 1662 - 1665
  • [10] Controlled synthesis of fullerenes and endohedral metallofullerenes in high frequency arc discharge
    Churilov, Grigory
    Popov, Alexey
    Vnukova, Natalia
    Dudnik, Alexander
    Samoylova, Natalia
    Glushenko, Gariy
    FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2016, 24 (11) : 675 - 678
123