Supramolecular hydrogen-bonding networks in cytosine salicylic acid hydrate (2 : 3 : 2) complex

被引:0
|
作者
B. Sridhar
K. Ravikumar
机构
[1] Indian Institute of Chemical Technology,Laboratory of Crystallography
来源
Crystallography Reports | 2010年 / 55卷
关键词
Salicylic Acid; Crystallography Report; Phthalic Acid; Phenyl Acetic Acid; Cambridge Crystallographic Data Centre;
D O I
暂无
中图分类号
学科分类号
摘要
Cytosine-cytosinium base pairs are interconnected by triple hydrogen bonds thereby resembling a pseudo-Watson-Crick pattern and generates two characteristic R22(8)-motifs. Both molecules of the salicylic acids interconnect the base pair and lead to the formation of one dimensional supramolecular hexameric tape along b-axis. This hexameric tape are sandwiched by the water molecules, one of the salicylic acid and salicylate anion which form one dimensional and two dimensional supramolecular hydrogen bonded networks in the crystal packing. Macrocylic rings of cavities are also noticed in the crystal structure.
引用
收藏
页码:240 / 246
页数:6
相关论文
共 50 条
  • [31] INTRAMOLECULAR HYDROGEN-BONDING .2. INTRAMOLECULAR HYDROGEN-BONDING AND TAUTOMERISM IN ORTHO-PHENYLAZOPHENOLS
    LI, SS
    FENG, HZ
    JIN, MJ
    CHEN, YH
    SHENG, HY
    ACTA CHIMICA SINICA, 1982, 40 (07) : 577 - 587
  • [32] A 3D Supramolecular Pd(II) Complex via Hydrogen-bonding and Weak M•••M Interactions
    Yan Chun-Feng
    Chen Lian
    Feng Rui
    Yang Ming
    Jiang Fei-Long
    Hong Mao-Chun
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (09) : 1099 - 1104
  • [33] Supramolecular photocyclodimerization of 2-hydroxyanthracene with a chiral hydrogen-bonding template, cyclodextrin and serum albumin
    Fukuhara, Gaku
    Umehara, Hiroaki
    Higashino, Saki
    Nishijima, Masaki
    Yang, Cheng
    Mori, Tadashi
    Wada, Takehiko
    Inoue, Yoshihisa
    PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2014, 13 (02) : 162 - 171
  • [34] Supramolecular photocyclodimerization of 2-hydroxyanthracene with a chiral hydrogen-bonding template, cyclodextrin and serum albumin
    Gaku Fukuhara
    Hiroaki Umehara
    Saki Higashino
    Masaki Nishijima
    Cheng Yang
    Tadashi Mori
    Takehiko Wada
    Yoshihisa Inoue
    Photochemical & Photobiological Sciences, 2014, 13 : 162 - 171
  • [35] INFLUENCE OF THE HYDROGEN-BONDING ON THE EXTRACTABILITY .2.
    BUVARI, A
    FOLDEAKI, E
    BARCZA, L
    MAGYAR KEMIAI FOLYOIRAT, 1979, 85 (05): : 199 - 202
  • [36] Supramolecular Complexation and Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylic Acid with 4-Aminoprolinol Derivatives as Chiral Hydrogen-Bonding Templates
    Kawanami, Yuko
    Pace, Tamara C. S.
    Mizoguchi, Jun-ichi
    Yanagi, Toshiharu
    Nishijima, Masaki
    Mori, Tadashi
    Wada, Takehiko
    Bohne, Cornelia
    Inoue, Yoshihisa
    JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (20): : 7908 - 7921
  • [37] Hydrogen-bonding patterns in 3-alkyl-3-hydroxyindolin-2-ones
    Becerra, Diana
    Insuasty, Braulio
    Cobo, Justo
    Glidewell, Christopher
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2010, 66 : O79 - O86
  • [38] The crystal structure of the molecular complex of 2′,6′-dimethoxyflavone with picric acid:: Alternating π-stacking and hydrogen-bonding interactions
    Lago, E
    Molins, E
    Miravitlles, C
    Wallet, JC
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2001, 31 (7-8) : 393 - 398
  • [39] Chromophoric Barbituric Acid Derivatives with Adjustable Hydrogen-Bonding Patterns as Component for Supramolecular Structures
    Bolz, Ina
    Batter, Mirko
    Rollberg, Anja
    Spange, Stefan
    MACROMOLECULAR SYMPOSIA, 2010, 287 : 8 - 15
  • [40] The crystal structure of the molecular complex of 2′,6′-dimethoxyflavone with picric acid: Alternating π-stacking and hydrogen-bonding interactions
    Elena Lago
    Elies Molins
    Carlos Miravitlles
    Jean-Claude Wallet
    Journal of Chemical Crystallography, 2001, 31 : 393 - 398