Kinetic regularities of the oxidation of crotonaldehyde with molecular oxygen in ethyl acetate

被引：0
作者：
Fedevich O.E. [1 ]
Levush S.S. [1 ]
Kit Yu.V. [1 ]
机构：
[1] State University l'Vivs'ka Politekhnika, 12 ul. S. Bandery
来源：
Theoretical and Experimental Chemistry | 1999年 / 35卷 / 5期
关键词：
Ethyl Acetate; Molecular Oxygen; Oxygen Partial Pressure; Kinetic Order; Crotonaldehyde;
D O I：
10.1007/BF02511122
中图分类号：
学科分类号：
摘要：
It has been established that the rate of oxidation increases linearly with increasing concentration of crotonaldehyde to 5 mol/L. An increase of the oxygen partial pressure to 0.1 MPa accelerated the oxidation process and the kinetic order with respect to oxygen is close to 0.6. The temperature dependence of the oxidation of crotonaldehyde and the accumulation of specific products have been established. The effects of reaction conditions on the selective accumulation ofcrotonic andpercrotonic acids have been analyzed. ©1999 Kluwer Academic/Plenum Publisher.
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页码：301 / 307
页数：6
相关论文
共 6 条
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