The enantioselective hydrogenation of N-acyl dehydroamino acids

被引：0
作者：
Ulrich Nagel
Judith Albrecht
机构：
[1] Universitaet Tuebingen,Institut fuer Anorganische Chemie II
来源：
Topics in Catalysis | 1998年 / 5卷
关键词：
asymmetric hydrogenation; amino acid precursors; transition metal complexes; homogeneous catalysis; heterogeneous catalysis; water soluble complexes; mechanism; catalytic cycles; origin of enantioselection;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The historical development of asymmetric hydrogenation of N-acyl dehydroamino acids and their derivatives is reported. Both homogeneous and heterogeneous catalysis are illustrated by selected examples. Catalysis by water soluble complexes and transfer hydrogenation are also treated in this review. The mechanism of catalytic hydrogenation, its elementary steps and the origin of enantioselection are discussed.
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页码：3 / 23
页数：20
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